中文摘要:本研究再次从葡萄穗霉中分离了普遍存在且高细胞毒性的大环内酯杆孢菌素E,并通过1-D和2-D核磁共振波谱法进行了表征。杆孢菌素E的光谱数据分配显示出与公认的文献有差异,而本文报道的光谱有助于将来的鉴定。本研究中杆孢菌素E结构的确定由晶体溶液提供尚属首次。
外文摘要:The commonly occurring, high‐cytotoxicity macrolide roridin E has been re‐isolated from Stachybotrys chartarum and characterized by 1‐D and 2‐D NMR spectroscopy. Assignment of the spectral data for roridin E revealed differences from the accepted literature, and spectra are reported herein to aid in future identification. For the first time confirmation of structure was provided by a crystallographic solution for roridin E.
外文关键词:trichothecene;roridin E; NMR analysis
作者:Ridge, CD;Mazzola, EP;Coles, MP;Hinkley, SFR
作者单位:Victoria Univ Wellington
期刊名称:MAGNETIC RESONANCE IN CHEMISTRY
期刊影响因子:1.226
出版年份:2017
出版刊次:4
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