中文摘要：植物保护仿制品严重影响着农作物产量、公共卫生以及食品贸易环境。据欧洲作物保护协会估计，目前欧盟和一些第三世界国家的植物保护市场假冒或非法植物保护产品分别占到5%-7%和20%-30%。本文对农药制剂中活性物质及其杂质的色谱测定方法进行了综述，旨在提高人们对制定植物保护产品认证及其解决方法的重要性的重视程度。本文概述了包括气相色谱法（GC）、高效液相色谱法（HPLC）、薄层色谱法（TLC）和离子色谱（IC）在内的多种色谱技术与不同检测器的应用，本章还强调了低分辨率和高分别率质谱法的应用潜力以及对多分析方法的应用需求。
外文摘要：Counterfeit plant protection products may cause losses of crops and threaten public health, food trade and the environment. As the European Crop Protection Association (ECPA) estimates, counterfeit and illegal plant protection products currently account for 5%-7% and 20%-30% of plant protection market in the EU and some third countries, respectively. The purpose of this review is to draw attention to the importance of authentication of formulated plant protection products and address the problem of their falsification. We summarize and discuss analytical methods that have been explored for determination of active substances and their impurities in pesticide formulations. We provide an overview of the application of different chromatographic techniques including gas chromatography (GC), high performance liquid chromatography (HPLC), thin layer chromatography (TLC) and ion chromatography (IC) with different detectors. The potential of using low and high resolution mass spectrometry and the need for multi-analyte methods is emphasized. (C) 2016 Elsevier B.V. All rights reserved.
外文关键词：Plant protection products, Counterfeit pesticides, Active substances, Impurities, Formulations, Chromatography, Detection, Mass spectrometry
作者：Plonka, Marlena; Walorczyk, Stanislaw; Miszczyk, Marek
作者单位：Natl Res Inst, Inst Plant Protect, Wladyslawa Wegorka 20, PL-60318 Poznan, Poland.
期刊名称：TRAC-TRENDS IN ANALYTICAL CHEMISTRY
期刊影响因子：7.487
出版年份：2016
出版刊次：12
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